Polarographic Studies of Uranyl-Fumarate Complex in Dimethyl Sulfoxide Solution
نویسندگان
چکیده
منابع مشابه
Dimethyl sulfoxide, diethyl fumarate solution for high dose dosimetry
Background: Dosimetry is a fundamental part of the radiation processing industry. Aqueous inorganic dosimeters have been used for gamma radiation dosimetry such as standard ferrous sulfate dosimeter. The purpose of this study was to investigate the effect of gamma radiation on the diethyl fumarate DEF in dimethyl sulfoxide DMSO solution and its possible use in chemical dosimetry. Materials and ...
متن کاملdimethyl sulfoxide, diethyl fumarate solution for high dose dosimetry
background: dosimetry is a fundamental part of the radiation processing industry. aqueous inorganic dosimeters have been used for gamma radiation dosimetry such as standard ferrous sulfate dosimeter. the purpose of this study was to investigate the effect of gamma radiation on the diethyl fumarate def in dimethyl sulfoxide dmso solution and its possible use in chemical dosimetry. materials and ...
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The first acidity scale to be established in a pure solvent other than water was the result of the pioneering work of Conant, Wheland, and McEwen in ether or ben~ene .~ During the past 20 years an ion-pair acidity scale covering an "effective pKa rangefrom about 15 to 40 has been developed in cyclohexylamine (CHA),6 and similar studies in other low-dielectric-constant solvents including 1,2-dim...
متن کاملA Polarographic Study of Uranyl-Salicylate and Uranyl-Phthalate Complex Formation in Acidie Solutions
The d. c. and a. c. polarography and cyclic voltammetry were applied to the study of uranyl-salicylate and uranyl-phthalate complexes. The study was limited to the pH range <5, because insoluble uranyl-hydroxydes are formed above this pH value. Uranyl-salicylate and -phthalate are irreversibly reduced. The electrode process is preceded by the chemical reaction of the complex with protons. By th...
متن کاملVibrational spectroscopic force field studies of dimethyl sulfoxide and hexakis(dimethyl sulfoxide)scandium(III) iodide, and crystal and solution structure of the hexakis(dimethyl sulfoxide)scandium(III) ion.
Hexakis(dimethyl sulfoxide)scandium(III) iodide, [Sc(OS(CH(3))(2))(6)]I(3) contains centrosymmetric hexasolvated scandium(III) ions with an Sc-O bond distance of 2.069(3) angstroms. EXAFS spectra yield a mean Sc-O bond distance of 2.09(1) angstroms for solvated scandium(III) ions in dimethyl sulfoxide solution, consistent with six-coordination. Raman and infrared absorption spectra have been re...
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ژورنال
عنوان ژورنال: Review of Polarography
سال: 1969
ISSN: 0034-6691,1884-7692
DOI: 10.5189/revpolarography.16.75